The Kermode fim review on 5
http://downloads.bbc.co.uk/podcasts/fivelive/kermode/rss.xml

Geekyness UK style; the gruff northern tones of Nate Lanxton are a breath of fresh tech air
http://podcasts.cnet.co.uk/CNET_co_uk_Podcast.rss

And top notch footie commentary from Phil Jupitus and The Times online crew.......
http://podcast.timesonline.co.uk/rss/thegamepodcastmp3.rss

PS on a techdad note, podcasts straight to your phone....definitely the way forward! My e63 has a totally good podcast client which beats faffing about and transfering from computer to device etc. blah blah yawn yawn